Plant-substrate biochar properties critical for mediating reductive debromination of 1,2-dibromoethane

作者: Jonathan H. Lindhardt*;Peter E. Holm;Yong-Guan Zhu;Changyong Lu;Hans Christian B. Hansen
通讯作者: Jonathan H. Lindhardt
作者机构: Department of Plant and Environmental Sciences, Faculty of Science, University of Copenhagen, Thorvaldsensvej 40, 1871 Frederiksberg C, Denmark
Key lab of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Sino-Danish Center for education and research, China and Denmark, Dalgas Avenue 4, DK-8000 Aarhus C., Denmark
通讯机构: Department of Plant and Environmental Sciences, Faculty of Science, University of Copenhagen, Thorvaldsensvej 40, 1871 Frederiksberg C, Denmark
Key lab of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China
Sino-Danish Center for education and research, China and Denmark, Dalgas Avenue 4, DK-8000 Aarhus C., Denmark
语种: 英文
关键词: Environmental remediation,Biochar,Persistent organic pollutants (POPs),Environmental catalysis,Green rust
期刊: 环境科学学报(英文版)
ISSN: 1001-0742
年: 2025
卷: 147
摘要: Dibromoethane is a widespread, persistent organic pollutant. Biochars are known mediators of reductive dehalogenation by layered FeII-FeIII hydroxides (green rust), which can reduce 1,2-dibromoethane to innocuous bromide and ethylene. However, the critical characteristics that determine mediator functionality are lesser known. Fifteen biochar substrates were pyrolyzed at 600 °C and 800 °C, characterized by elemental analysis, X-ray photo spectrometry C and N surface speciation, X-ray powder diffraction, specific surface area analysis, and tested for mediation of reductive debromination of 1,2-dibromoethane by a green rust reductant under anoxic conditions. A statistical...

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