Investigation into enhanced performance of toluene and Hg0 stimulative abatement over Cr-Mn oxides co-modified columnar activated coke
作者:
Jiajie Wang;Jie Liu;Lei Gao*;Dong Xie;Caiting Li;...
通讯作者:
Lei Gao
作者机构:
School of Resources Environment and Safety Engineering, University of South China, Hengyang 421001, China
National & Local Joint Engineering Research Center for Airborne Pollutants Control and Radioactivity Protection in Buildings, Hengyang 421001, China
Key Laboratory of Prefabricated Building Energy Saving Technology of Hunan Province, Hengyang 421001, China
College of Environmental Science and Engineering, Hunan University, Changsha 410082, China
通讯机构:
School of Resources Environment and Safety Engineering, University of South China, Hengyang 421001, China
National & Local Joint Engineering Research Center for Airborne Pollutants Control and Radioactivity Protection in Buildings, Hengyang 421001, China
Key Laboratory of Prefabricated Building Energy Saving Technology of Hunan Province, Hengyang 421001, China
College of Environmental Science and Engineering, Hunan University, Changsha 410082, China
语种:
英文
期刊:
环境科学学报(英文版)
ISSN:
1001-0742
年:
2025
卷:
148
页码:
88-106
摘要:
In this study, a string of Cr-Mn co-modified activated coke catalysts (XCryMn1-y/AC) were prepared to investigate toluene and Hg0 removal performance. Multifarious characterizations including XRD, TEM, SEM, in situ DRIFTS, BET, XPS and H2-TPR showed that 4%Cr0.5Mn0.5/AC had excellent physicochemical properties and exhibited the best toluene and Hg0 removal efficiency at 200℃. By varying the experimental gas components and conditions, it was found that too large weight hourly space velocity would reduce the removal efficiency of toluene and Hg0. Although O2 promoted the abatement of toluene and Hg0, the inhibitory role of H2O and SO2 offset the promoting effect of O2 to s...